Evaluating the Sources and Fate of Nitrate in the Alluvial Aquifers in the Shijiazhuang Rural and Suburban Area, China: Hydrochemical and Multi-Isotopic Approaches

The identification of the sources and fate of NO contaminants is important to protect the water quality of aquifer systems. In this study, NO contaminated groundwater from the drinking water wells in the Shijiazhuang area, China, was chemically (NO /Cl− ratio) and isotopically (δ15NNO3, δ18ONO3 and δ13CDOC; δ2HH2O, δ18OH2O) characterized to identify the sources of NO and address subsequent biogeochemical processes. The positive correlations between dominant anions and cations suggested that the dissolution of calcium carbonate and gypsum minerals was the most effective process in the groundwater. Elevated concentrations of NO , Cl− and Mg2+ could be related to the wastewater irrigation and usage of fertilizers. The natural water in the study area originated primarily from precipitation and experienced a limited extent of evaporation, as demonstrated by measurements of δ2HH2O and δ18OH2O. A cross-plot of δ15NNO3 vs. δ18ONO3 gave an enrichment of the 15N isotope relative to the 18O isotope by a factor of 2. A further insight into the denitrification process was obtained by the synergistic changes in δ13CDOC and δ15NNO3 values, confirming that a low extent of denitrification occurred. Nitrification processes were evaluated by means of δ18ONO3 and δ18OH2O. The initial δ15NNO3 value(s) of the NO source(s) were roughly estimated between 2‰ and 5‰. Based on the level of natural NO , anthropogenic activities were OPEN ACCESS Water 2015, 7 1516 considered the main reason for the elevated NO concentration of the shallow groundwater. NH fertilizers were the major source of NO in the non-wastewater irrigated area, while wastewater was regarded as the primary source of NO in the wastewater-irrigated area. A low content of NO in deep groundwater might mainly be influenced by precipitation and soil organic N that was involved in denitrification reactions. Some of the deep groundwater samples could have been contaminated by wastewater. The mixing process of multiple NO sources was identified as another important factor affecting the NO concentration of the groundwater in the study area. The combined use of δ15NNO3, δ18ONO3 and δ13CDOC results and hydrochemical data (NO /Cl− ratios) gives an insight into the mixing effect of different NO sources and processes affecting NO concentration under conditions of intensive land-use activities.